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Tesoro Anacortes: hydrogen attack in steel

The steel was nearly forty years old. The damage was inside it.

Key facts: Anacortes refinery, Washington, 2 Apr 2010; Seven employees fatally injured; Nearly forty-year-old heat exchanger failed; Direct cause: high temperature hydrogen attack (HTHA); Failed during a stream-switch maintenance task; CSB recommendations on HTHA standards, 16 listed

What happened

On 2 April 2010 at the Tesoro refinery in Anacortes, Washington, a nearly forty-year-old heat exchanger catastrophically failed during a maintenance operation to switch a process stream between two parallel banks of exchangers. Seven employees were fatally injured.

What the CSB found

The US Chemical Safety Board (CSB) found that the explosion resulted from high temperature hydrogen attack (HTHA) damage to the heat exchanger. The Board approved its final report 3-0 on 1 May 2014. Its recommendations went to API, the US EPA, the Washington Governor and Legislature, Washington L&I, Tesoro and the union local, and covered HTHA-related standards, inherently safer systems analysis, process hazard analysis, integrity operating windows, damage mechanism hazard reviews and process safety culture surveys.

What it means

HTHA is damage inside carbon steel that has been exposed to hydrogen at elevated temperature. It does not announce itself as thinning or as a surface crack, so a corrosion-rate survey is the wrong tool for it. In our view the main lesson is organisational as well as metallurgical: a damage mechanism that the plant has decided is not credible is the one that no inspection plan looks for, and the first sign may be the failure.

This article does not repeat details the CSB incident page does not state, such as operating conditions. For those, read the CSB report.

What an engineer should check

Source. US Chemical Safety Board (CSB), Tesoro Anacortes Refinery Explosion and Fire, 2 April 2010 (final report approved 1 May 2014). CSB incident page. This article summarises the sources in our own words; see the originals for full details. It is general technical information, not advice on a specific component.

Related reading

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